%0 Journal Article %T Degradation of 2,4-Dichlorophenol in Aqueous Solution by ZVI/EDDS/Air System
ZVI/EDDS/Air体系降解水中2,4-二氯酚的研究 %A SUN Qian %A ZHOU Hai-yan %A CAO Meng-hu %A WU Lin-n %A WANG Lin-ling %A CHEN Jing %A LU Xiao-hua %A
孙倩 %A 周海燕 %A 曹梦华 %A 吴琳娜 %A 王琳玲 %A 陈静 %A 陆晓华 %J 环境科学 %D 2012 %I %X A new oxidation system of Fenton-like system (ZVI/EDDS/Air) has been developed to degrade 2,4-chlorophenols (2,4-DCP) in aqueous solution. The influences of initial conditions, i. e., EDDS concentration, iron dosage, aeration rate, 2,4-DCP concentration and pH as well as reaction temperature on the degradation of 2,4-DCP were studied. The results demonstrated that this ZVI/EDDS/Air system was able to effectively degrade 2,4-DCP in aqueous solution, and the degradation of 2,4-DCP conforms to the pseudo-first-order reaction kinetics equation. Removal of above 99% 2,4-DCP was achieved in ZVI/EDDS/Air system at room temperature and pressure after 1 h reaction when the initial conditions were 2,4-DCP 100 mg·L-1, EDDS 0.80 mmol·L-1, ZVI 20 g·L-1, aeration rate 2 L·(min·L)-1. Compared with ZVI/EDTA/Air system, ZVI/EDDS/Air system showed higher efficiency in the degradation of 2,4-DCP at ambient circumstance and was more environmentally benign. %K ZVI %K EDDS %K 2 %K 4-dichlorphenol %K degradation %K Fenton-like system
零价铁 %K 乙二胺二琥珀酸 %K 2 %K 4-二氯酚 %K 降解 %K 类Fenton体系 %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=3FF3ABA7486768130C3FF830376F43B398E0C97F0FF2DD53&cid=A7CA601309F5FED03C078BCE383971DC&jid=64CD0AA99DD39F69401C615B85F123EF&aid=721AF616C5F2DD3E7A6C6A8393046A10&yid=99E9153A83D4CB11&vid=27746BCEEE58E9DC&iid=708DD6B15D2464E8&sid=AD07B495A9DBD65C&eid=C7A88C2E4A45A81E&journal_id=0250-3301&journal_name=环境科学&referenced_num=0&reference_num=29