%0 Journal Article
%T Chlorination Byproducts Formation Potentials of Typical Nitrogenous Organic Compounds in Water<br>水中典型含氮有机物氯化生成消毒副产物的潜能研究
%A XU Qian
%A XU Bin
%A QIN Cao
%A XIA Sheng-ji
%A GAO Nai-yun
%A TIAN Fu-xiang
%A LI Da-peng
%A <br>徐倩
%A 徐斌
%A 覃操
%A 夏圣骥
%A 高乃云
%A 田富箱
%A 李大鹏
%J 环境科学
%D 2011
%I 
%X Twelve typical nitrogenous organic compounds including herbicides, pesticides, amino acids, industrial products etc in polluted raw water were selected to investigate formation of typical carbonaceous and nitrogenous DBPs during chlorination and chloramination. To indentify the formation mechanism of carbonaceous and nitrogenous disinfection byproducts from nitrogenous chemicals, chlorination and chloroamination of urea herbicides, triazine herbicides, amino acid, and other compounds were investigated. As a result, the potential precursors for different DBPs were defined as well. It has been identified that widely used urea herbicides could produce as many as 9 specific DBPs. The chlorotoluron shows highest reactivity and yields chloroform (CF), monochloroacetic acid (MCAA), dichloroacetic acid (DCAA), 1,1-dichloro-acetone (1,1-DCP), 1,1,1-trichloro-acetone (1,1,1-TCP), chloropicrin (NTCM), dichloro-acetonitrile (DCAN), dimethylnitrosamine (NDMA). The results indicated that aldicarb and dinoseb are important precursors of CF, DCAA, MCAA, NTCM as well. High concentrations of CF and DCAA were found during L-tryptophan chlorination. Furthermore, DBPs formation pathways and mechanisms were suggested during chlorination and chloramination of chlorotoluron, ametryn, dinoseb L-tryptophan.
%K nitrogenous organic compounds
%K chlorination disinfection
%K chloramine disinfection
%K disinfection DBPs
%K NDMA<br>含氮有机物
%K 氯化消毒
%K 氯胺消毒
%K 消毒副产物
%K NDMA
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=3FF3ABA7486768130C3FF830376F43B398E0C97F0FF2DD53&cid=A7CA601309F5FED03C078BCE383971DC&jid=64CD0AA99DD39F69401C615B85F123EF&aid=3080FA4F2C89FF5D7EC228BCCBD191D7&yid=9377ED8094509821&vid=9971A5E270697F23&iid=DF92D298D3FF1E6E&sid=E641A1E50E600569&eid=2CF50ACB94270F08&journal_id=0250-3301&journal_name=环境科学&referenced_num=0&reference_num=0