%0 Journal Article %T Radiolysis of Aqueous Solution of Thiocyanate by Y-Rays
硫氰根的γ射线辐照降解研究 %A FENG Hai-bing %A YANG Ming-de %A HU Hu-sheng %A HUANG Hui-ping %A
冯海兵 %A 杨明德 %A 胡湖生 %A 黄慧萍 %J 环境科学 %D 2008 %I %X Radiolysis of aqueous solution of thiocyanate by 60Co gamma-rays was studied. In condition of pH = 1 and pH = 3,25 mg/L SCN- was decomposed under the dose of 6 kGy, with decomposition rate of 98.11% (pH = 1) and 95.97% (pH = 3) respectively. 25 mg/L SCN- (pH = 7) was decomposed under the dose of 9 kGy and the decomposition rate is 99.33%. In the alkaline condition, pH = 10 and pH = 12, the dose of 18 kGy was need, and the decomposition rate is 99.64% and 99.93% respectively. High SCN- concentration means that more radiation dose is need. From the comparison of before radiolysis and after radiolysis's TOC (total organic carbon) and TN (total nitrogen) of SCN- solution, little TOC and TN was removed. The determination of SO4(2-) and NO3- concentration indicated that sulfur element was removed and converted to SO4(2-), and nitrogen element rarely converted to NO3-, but converted to other forms of nitrogen. %K γ射线 %K SCN- %K 辐照 %K 降解 %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=3FF3ABA7486768130C3FF830376F43B398E0C97F0FF2DD53&cid=A7CA601309F5FED03C078BCE383971DC&jid=64CD0AA99DD39F69401C615B85F123EF&aid=8384AA7066CB1C52DA10B00BCE22F8F3&yid=67289AFF6305E306&vid=771469D9D58C34FF&iid=B31275AF3241DB2D&sid=6DC9B9BB39B3E540&eid=1593278DEEDA4D8F&journal_id=0250-3301&journal_name=环境科学&referenced_num=0&reference_num=12