%0 Journal Article
%T Detection of Hydroxyl Radical in Heterogeneous Photo-Fenton System Using the Fluorescence Technique and Influencing Factor Study<br>光助非均相芬顿体系中羟基自由基的荧光光谱法测定与影响因素研究
%A LIU Ting
%A YOU Hong
%A CHEN Qi-wei
%A WANG Zhi-chao
%A <br>刘婷
%A 尤宏
%A 陈其伟
%A 汪志超
%J 环境科学
%D 2009
%I 
%X The Fe_2O_3/TiO_2/Al_2O_3 catalyst was prepared by using TiO_2/Al_2O_3 as carrier and the heterogeneous photo-Fenton system was established in the three-phase fluidized bed. A fluorescence technique was developed for the determination of the hydroxyl radicals (·OH) from the heterogeneous photo-Fenton system, using coumarin as the fluorescence probe. In addition, four main factors, namely pH, H_2O_2 concentration, catalyst loading and UV light intensity, which could influence the concentration of ·OH produced during the reaction process, was also discussed. The fluorescence method using coumarin as the fluorescence probe was demonstrated to be capable of detecting ·OH generated in heterogeneous photo-Fenton system with veracity and high reproducibility. It was also found that the ·OH generated in heterogeneous photo-Fenton system conformed to the zero reaction dynamics in 30 min. Moreover, the pH, H_2O_2 concentration, catalyst loading and UV light intensity influenced the ·OH generated during the reaction process.
%K fluorescence
%K coumarin
%K heterogeneous catalysis
%K photo-Fenton
%K hydroxyl radical<br>荧光光谱法
%K 香豆素
%K 非均相催化
%K 光-芬顿体系
%K 羟基自由基
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=3FF3ABA7486768130C3FF830376F43B398E0C97F0FF2DD53&cid=A7CA601309F5FED03C078BCE383971DC&jid=64CD0AA99DD39F69401C615B85F123EF&aid=9B461A424879C11FCF5AF050753BFDB0&yid=DE12191FBD62783C&vid=340AC2BF8E7AB4FD&iid=9CF7A0430CBB2DFD&sid=B287A1A04CD05645&eid=4D701CE46BA72F2B&journal_id=0250-3301&journal_name=环境科学&referenced_num=0&reference_num=21