%0 Journal Article
%T DBPs Formation Characteristics in Chlorinating and Relationship with Chemical Structure of Some Aromatic Organic Matter<br>芳香类有机物生成氯化消毒副产物特性及其与化学结构的关系
%A WANG Xiao-wen
%A ZHANG Xiao-jian
%A CHEN Chao
%A HAO Xiaofei
%A <br>王小文
%A 张晓健
%A 陈超
%A 郝晓飞
%J 环境科学
%D 2006
%I 
%X Some organic matter that have aromatic structure similar as humic acid are selected to conduct chlorination test, determined the formation of HAAs and THMs of tested matters, researched the relationship of the chemical structure of DBPFP with DBPs formation characteristics. The results indicated that: (1) The sequence of HAAs formation activity is p-Hydroxybenzoic acid > p-Aminoacetophenone > o-Benzenediol > m-Benzenediol; and THMs' s is m-Benzenediol > p-Aminoacetophenone > 2-Hydroxy-p-aminoacetophenone > p-Hydroxybenzoic acid. (2) The sequence of earlier chlorination reaction rate of HAAs is m-Benzenediol > p-Aminoacetophenone > p-Hydroxybenzoic acid > o-Benzenediol; and THMs' s is p-Hydroxybenzoic acid > 2-Hydroxy-p-aminoacetophenone > m-Benzenediol > p-Aminoacetophenone. (3) The substances that having the substituent group structure of para and ortho position are mostly format HAAs, and one's of having meta position are mostly format THMs. (4) On the benzene ring, hydroxyl group has the highest activity of forming DBPs, and the second is ketone group; amino-group is play a part of auxiliary forming para, ortho or meta position structure mainly; aldehyde and carboxyl group are inert function group; the function of methyl group is remain to be determined.
%K aromatic organic matter
%K chlorination activity
%K HAAs
%K THMs
%K chemical structure<br>芳香类有机物
%K 氯化活性
%K 卤乙酸
%K 三卤甲烷
%K 化学结构
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=3FF3ABA7486768130C3FF830376F43B398E0C97F0FF2DD53&cid=A7CA601309F5FED03C078BCE383971DC&jid=64CD0AA99DD39F69401C615B85F123EF&aid=225DC362E992B0D3&yid=37904DC365DD7266&vid=DB817633AA4F79B9&iid=5D311CA918CA9A03&sid=2E97FDBA239991ED&eid=BF7851EF606736C9&journal_id=0250-3301&journal_name=环境科学&referenced_num=0&reference_num=9