%0 Journal Article %T Dechlorination of p-Dichlorobenzene by Metallic Catalytic Reduction Technology
金属催化还原技术对p-二氯苯的脱氯 %A XU Xin-hu %A ZHOU Hong-yi %A WANG Da-hui %A
徐新华 %A 周红艺 %A 汪大翚 %J 环境科学 %D 2004 %I %X Pd/Fe bimetallic catalysts were synthesized by chemical deposition and used to dechlorination treatment of p-DCB. Batch experiments demonstrated that the Pd/Fe bimetallic particles can effectively dechlorinate p-DCB. Dechlorination efficiency accounted for more than 90% at Pd weight ratio (Pd to Fe) 0.02% and metal to solution ratio about 4g/74mL in 90min. Dechlorination ratios were affected by reaction temperature, initial pH, Pd ratio and the addition of Pd/Fe. Chlorobenzene represented stable partially dechlorinated intermediates in the generation of benzene. %K Pd/Fe bimetal %K catalytic redution %K dechlorination %K p-DCB
钯/铁双金属 %K 催化还原 %K 脱氯 %K p-二氯苯 %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=3FF3ABA7486768130C3FF830376F43B398E0C97F0FF2DD53&cid=A7CA601309F5FED03C078BCE383971DC&jid=64CD0AA99DD39F69401C615B85F123EF&aid=3815753BD6F104F0&yid=D0E58B75BFD8E51C&vid=C5154311167311FE&iid=B31275AF3241DB2D&sid=C3BF5C58156BEDF0&eid=74011071555EB4E5&journal_id=0250-3301&journal_name=环境科学&referenced_num=8&reference_num=12