%0 Journal Article %T SYNTHESIS AND THERMAL STABILITY OF PHOSPHAPHENANTHRENE-CONTAINING POLYACETYLENES
含膦酰杂菲侧基聚乙炔的合成与热稳定性 %A SHEN Jinbo %A TONG Bin %A ZHAO Wei %A PAN Yuexiu %A FENG Xiao %A SHI Jianbing %A ZHI Junge %A DONG Yuping %A
申进波 %A 佟斌 %A 赵玮 %A 潘月秀 %A 冯霄 %A 石建兵 %A 支俊格 %A 董宇平 %J 高分子学报 %D 2009 %I %X New thermal stable mono-substituted polyacetylenes (PAT5 and PAT10) containing phosphaphenanthrene as side groups and end-chains of different lengths were studied.4-Ethynylbenzoyl and 4-alkoxylbenzoyl were first introduced into the 2-(6-oxide-6H-dibenz<1,2>oxaphos-phorin-6-yl)-dihydroxyphenylene (ODOPB) through a two-step esterification,respectively,which synthesized the phosphaphenanthrene-containing acetylenic monomers.The polymerization of novel monomers was carried out by using Rh(nbd)Cl]2-NEt3 as... %K Polyacetylene %K Rh-based catalyst %K Phosphaphenanthrene %K Thermal stability
聚乙炔 %K Rh基催化剂 %K 磷酰杂菲 %K 热稳定性 %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=15971983683C7643EE80F1CE621DEB60&aid=2B1DBD2CF1EF40C8677F23969843BD25&yid=DE12191FBD62783C&iid=5D311CA918CA9A03&sid=CA122BD5B2FF2137&eid=786A9BAE5CF9B9EE&journal_id=1000-3304&journal_name=高分子学报&referenced_num=1&reference_num=29