%0 Journal Article
%T ELECTROCHEMICAL POLYMERIZATION OF ACENAPHTHENE IN BORON TRIFLUORIDE DIETHYL ETHERATE CONTAINING POLYETHYLENE GLYCOL OLIGOMERS<br>1,8-亚乙基萘在三氟化硼乙醚-聚乙二醇中的电化学聚合
%A LIU Houting
%A XU Jingkun
%A ZHOU Weiqiang
%A PU Shouzhi
%A WEI Zhenhong
%A SHEN Liang
%A LUO Mingbiao
%A <br>刘厚亭
%A 徐景坤
%A 周卫强
%A 蒲守智
%A 魏振宏
%A 申亮
%A 罗明标
%J 高分子学报
%D 2007
%I 
%X A novel dark brown polyacenaphthene film has been electrodeposited on platinum electrode by direct anodic oxidation of acenaphthene in mixed electrolyte of boron triflouride diethyl etherate(BFEE) and polyethylene glycol oligomers with a molecular weight of 400(PEG 400).The oxidation potential of acenaphthene in this medium was initiated at approximately 0.95 V versus SCE,which was much lower than that determined in acetonitrile containing 0.1 mol\5L~(1) Bu_4NBF_4(1.38 V versus SCE).The introduction of PEG 400 improved the solubility of the monomer in the mixed electrolytes.The structure of the polymer was investigated by UV-Vis,FTIR and()~1H-NMR.Fluorescent spectral studies indicated that polyacenaphthene film was a blue light emitter both in DMSO solutions and in solidstate.
%K Polyacenaphthene
%K Conducting polymers
%K Electrochemical polymerization
%K Boron trifluoride diethyl etherate
%K Fluorescence properties<br>聚(1
%K 8-亚乙基萘)
%K 导电高分子
%K 电化学聚合
%K 三氟化硼乙醚
%K 荧光
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=15971983683C7643EE80F1CE621DEB60&aid=D69C6C0BC7280239&yid=A732AF04DDA03BB3&iid=B31275AF3241DB2D&sid=D8414BC1307BF1A3&eid=C7A2B92569DF5458&journal_id=1000-3304&journal_name=高分子学报&referenced_num=0&reference_num=25