%0 Journal Article
%T THE CONTROLLED SYNTHESIS OF POLYANILINE MICROTUBES WITH SQUARE INNER CROSS-SECTION AND POLYAZANE SQUARE MICROBARS<br>聚苯胺内方形微米管和方形微米棒的可控制备和结构
%A LI Jiuming
%A ZHU Ying
%A XIE Qiang
%A WAN Meixiang
%A JIANG Lei
%A <br>李久明
%A 朱英
%A 解强
%A 万梅香
%A 江雷
%J 高分子学报
%D 2008
%I 
%X 以柠檬酸为掺杂剂、过硫酸铵为氧化剂,通过改变苯胺单体的浓度实现了聚苯胺微/纳米结构的可控的自组装制备.在较高苯胺单体浓度时,自组装得到具有内方形的导电态聚苯胺微米管,其直径约为580-300nm,管壁厚约为80 nm.而在极稀的苯胺单体浓度时,自组装得到正方形横截面的方形微米棒,其横截面的边长约为690～290 nm,长度约为1-40um.结构表征结果证明,所得的微米方形棒是N-N单键结合的聚氮烷;而延长聚合反应时间,则可得到本征态聚苯胺微米管.
%K Polyaniline
%K Polyazane
%K Microtubes with inner square cross-section
%K Microbars with square cross-section
%K Self-assembly process<br>聚苯胺
%K 聚氮烷
%K 内方形微米管
%K 微米方形棒
%K 氧化聚合
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=15971983683C7643EE80F1CE621DEB60&aid=8BA4B069C887650930F6E3D22C321B31&yid=67289AFF6305E306&iid=708DD6B15D2464E8&sid=AE9D5375B9B2D7F2&eid=1A775ABEB80E436B&journal_id=1000-3304&journal_name=高分子学报&referenced_num=2&reference_num=21