%0 Journal Article
%T SYNTHESIS OF HELICAL POLY(N-PROPARGYLAMIDE)S AND EFFECTS OF PENDENT GROUPS ON THE STABILITY OF HELICES<br>螺旋聚（N-炔丙基酰胺）的合成及侧基对螺旋结构稳定性影响
%A DENG Jianping
%A ZHAO Weiguo
%A YANG Wantai
%A <br>邓建平
%A 赵伟国
%A 杨万泰
%J 高分子学报
%D 2007
%I 
%X Three N-propargylamide monomers with different pendent groups were synthesized and characterized with NMR,IR and elemental analysis techniques.These monomers were polymerized with Rh-catalyst in high yields(nearly 100%),and the obtained polymers demonstrated high steroregularity.The secondary structures of the resulting polymers were examined by UV-Vis spectroscopy.The different pendent groups in the polymers' side chains placed different effects on the stability of the helices adopted by the corresponding polymers.It was concluded that the pendent groups affected largely both the formation of intramolecualr hydrogen bonds between the neighboring amide groups and the rigidity of the polymer main chains.These two factors are exceptionally important for poly(N-paropargylamides) to take the configuration of stable helices.
%K N-propargylamide
%K Helical polymer
%K Rh catalyst
%K Hydrogen bonding
%K Steric repulsion<br>N-炔丙基酰胺
%K 螺旋聚合物
%K 铑催化剂
%K 氢键
%K 空间位阻
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=15971983683C7643EE80F1CE621DEB60&aid=B48219F524B8238C&yid=A732AF04DDA03BB3&iid=B31275AF3241DB2D&sid=20ADD38F841C6A4B&eid=A726E84831FE609B&journal_id=1000-3304&journal_name=高分子学报&referenced_num=1&reference_num=27