%0 Journal Article
%T EXPERIMENTAL AND THEORETICAL INVESTIGATIONS ON THE ELECTROCHEMICAL POLYMERIZATION OF ORTHO-DISUBSTITUTED BENZENE<br>邻二取代苯电化学氧化聚合的实验及理论计算研究
%A ZENG Liqiang
%A LI Yuzhen
%A XU Jingkun
%A LE Zhanggao
%A WANG Baoshan
%A MA Mulin
%A <br>曾理强
%A 李玉真
%A 徐景坤
%A 乐长高
%A 王宝山
%A 马木林
%J 高分子学报
%D 2009
%I 
%X The electrochemical polymerizations of a series of ortho-disubstituted benzenes were investigated by experimental and theoretical approaches.The results indicated that o-dihydroxybenzene((oHDB),)o-dimethoxybenzene (oDMOB) and 1-hydroxy-2-methoxybenzene(HMOB) in pure boron trifluoride diethyl etherate(BFEE) can be succefully electropolymerized.The~1H,~(13)C-NMR spectra of these monomers and their corresponding polymers proved that the polymerization occurred mainly at C_4 and C_5 positions.However the others...
%K HOMO-LUMO<br>电化学聚合
%K 邻二取代苯
%K 理论研究
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=15971983683C7643EE80F1CE621DEB60&aid=8A3A96A5395AD34C4D6E92ADF84E7244&yid=DE12191FBD62783C&iid=38B194292C032A66&sid=79D2EF35F60110C2&eid=1B64850025D0BBBE&journal_id=1000-3304&journal_name=高分子学报&referenced_num=0&reference_num=15