%0 Journal Article
%T STUDIES ON THE ADSORPTION PROBLEMS OF POROUS SILICA GELS FOR GPC<br>凝胶渗透色谱多孔硅胶吸附问题的研究
%A Yang Ya-jun
%A Bei Jian-zong
%A Zhang Xing-hua
%A <br>杨亚君
%A 贝建中
%A 张兴华
%J 高分子学报
%D 1980
%I 
%X The relationship between the content of hydroxyl groups on the surface of porous silica gels used as packings for GPC and the adsorption effects was investigated. Toluene was used as eluent and hydroxyl-end blocked polydimethylsiloxane as polymer sample. By modifying the porous silica gels with hexamethyldisilazane or by adding a small amount of a suppressant to the solvent carrier to reduced the adsorpting of polymers onto the surface of gels, was found to be unsatisfactory. An effective method for suppressing the adsorption by blocking the hydroxyl groups on the ends of polymer chains with trimethylchlorosilane has been proposed.
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=15971983683C7643EE80F1CE621DEB60&aid=C0FA4D3D44A46810&yid=E56875464B1C0EC1&iid=B31275AF3241DB2D&sid=C7DDDE86E6286CD9&eid=381FB4265090A8E0&journal_id=1000-3304&journal_name=高分子学报&referenced_num=0&reference_num=0