%0 Journal Article
%T KINETIC STUDIES ON COORDINATION POLYMERIZATION OF BUTADIENE VIA REAL-TIME ART-FTIR MONITORING<br>原位ATR-FTIR法研究丁二烯配位聚合反应动力学
%A ZHAO Jiangwei
%A ZHU Han
%A WU Yixian
%A JIAN Rui
%A YANG Wantai
%A WU Guanying
%A <br>赵姜维
%A 朱寒
%A 吴一弦
%A 简睿
%A 杨万泰
%A 武冠英
%J 高分子学报
%D 2010
%I 
%X FTIR spectroscopy in combination with a diamond tipped attenuated total reflectance(ATR) immersion probe was utilized to study in situ coordination polymerization of butadiene(Bd) in hexane(HEX) with Neodymium-based catalyst.The relationship of their intensity at signal bands of Bd and its concentration were investigated.The kinetic studies of polymerization of Bd were conducted by in situ ATR-FTIR.The signal band at 1592 cm~(-1) was assigned to the stretching vibration of Bd,and the signal bands at 1010 cm...
%K ATR-FTIR
%K Real-time monitoring
%K Butadiene
%K Coordination polymerization<br>全反射傅立叶红外光谱
%K 原位
%K 丁二烯
%K 配位聚合
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=15971983683C7643EE80F1CE621DEB60&aid=936C5BA8965A1E045F5D3779F361C327&yid=140ECF96957D60B2&iid=0B39A22176CE99FB&sid=CC0ECB9C52F1B85F&eid=CEC789B3C68C3BB3&journal_id=1000-3304&journal_name=高分子学报&referenced_num=0&reference_num=15