%0 Journal Article
%T THE MORPHOLOGY AND GLASS TRANSITION BEHAVIOR OF THE POLYBUTADIENE-BASED POLYURETHANE/POLYSTYRENE (OR POLYMETHYL METHAC- RYLATE) INTERPENETRATINGPOLYMER NETWORK<br>端羟基聚丁二烯型聚氨酯/聚苯乙烯(或聚甲基丙烯酸甲酯)互穿网络的形态和玻璃化转变
%A XUE Shu-chang
%A ZHANG Zhi-ping
%A YING Sheng-kang
%A <br>薛曙昌
%A 张志平
%A 应圣康
%J 高分子学报
%D 1989
%I 
%X The morphology structure and glass transition behavior of polybutadiene-based polyuretha-ne/polystyrene (or polymethyl methacrylate) interpenetrating polymer network (PU(HTPB)/ PSt-IPN, PU(HTPB)/PMMA-IPN) were investigated by TEM and DSC. TEM showed that the phase inversion of PU(HTPB)/PSt-IPN occurred in the concentration of 25% PU(HTPB), and the size of dispersed phase domains of the IPN formed was smaller in the concentration about 50% PU(HTPB). Increasing DVB content or proportion of NCO to OH enhanced in-terpenetration of two components. All of IPN samples exhibited special cellular structure. According to the fact that PU(HTPB) was formed first,a formation mechanism of the struc-ture was proposed.
%K 聚氨酯
%K 聚苯乙烯
%K PMMA
%K IPN
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=15971983683C7643EE80F1CE621DEB60&aid=C71650CF9C10407BB976F675980DE146&yid=1833A6AA51F779C1&iid=94C357A881DFC066&sid=E6A0A363CA4FC5CF&eid=F8AEC975DBDD7F2F&journal_id=1000-3304&journal_name=高分子学报&referenced_num=0&reference_num=1