%0 Journal Article
%T THE EFFECT OF AMINE ON THE RADICAL POLYMERIZATION INITIATED WITH ORGANIC PEROXIDES<br>胺对有机过氧化物引发聚合的影响
%A Qiu Kun-yuan
%A Zhang Jing-yi
%A Feng Xin-de
%A <br>丘坤元
%A 张景义
%A 冯新德
%J 高分子学报
%D 1984
%I 
%X In this paper, the radical polymerization of methyl methacrylate (MMA) initiated with benzoyl peroxide (BPO), lauroyl peroxide (LPO), t-butyl hydroperoxide (TBH), t-butyl peroxybenzoate (TBPB) and the effect of amine on the radical polymerization rate were studied, respectively. It was found that the order of polymerization rate Rp was as follows: LPO > BPO > TBH > TBPB. In the presence of tertiary amine such as N, N-di-methyl-p-toluidine (DMT), N-ethyl piperidine (NEP), the amine promoted the polymerizatio of MMA,and the order of Rp changed to BPO-amine>LPO-amine>TBH-amine>TBPB-amine.
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=15971983683C7643EE80F1CE621DEB60&aid=03C8831C6FC1000725468BBCA4A84952&yid=36250D1D6BDC99BD&iid=CA4FD0336C81A37A&sid=E44E40A2398D4F2A&eid=E203FB1A272C9DD2&journal_id=1000-3304&journal_name=高分子学报&referenced_num=0&reference_num=0