%0 Journal Article
%T SYNTHESIS OF SILICON MONOMERS AND OLIGOMERS CONTAINING CYCLOHEXYLENE RING<br>含次环己基的有机硅单体及其低聚体的合成
%A Lu Feng-cai
%A Wang Bao-ren
%A Gao Yuan-ming
%A Chen Su-ming
%A Li Zong-yu
%A <br>卢凤才
%A 王葆仁
%A 高元明
%A 陈素明
%A 李宗禹
%J 高分子学报
%D 1984
%I 
%X 1,3-Bis (trichlorosilyl) cyclohexance was obtained by addition HSiCl3 to cyclohexa-diene-1,3 in the presence of H2PtCl6·6H2O in isopropyl alcohol. The new compound was ethanolysed and methylated to form di-methyl tetra-ethoxy disilyl, tri-methyl tri-etKoxy disilyl and tetra-methyl di-ethoxy disilyl cyclohexanes.The di- to tetra-functional monomers were hydrolysed by hydrochloric acid in ether. The di-functional monomers yielded cyclic dimer similar to octamethylcyclotetrasiloxane, and the tri-functional monomer,a cyclic tetramer,while in thecase of tetra-functional monomer,a cyclic octamer was obtained.All these compounds have not been reported in literature.
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=15971983683C7643EE80F1CE621DEB60&aid=93C7BF9B8019FBD2&yid=36250D1D6BDC99BD&iid=B31275AF3241DB2D&sid=6D6BFCF0101BC091&eid=08076B8B3CC96095&journal_id=1000-3304&journal_name=高分子学报&referenced_num=0&reference_num=0