%0 Journal Article
%T SYNTHESIS, POLYMERIZATION AND FLUORESCENCE BEHAVIOR OF N-(2-VINYLOXYETHYL)-1,8- NAPHTHALIMIDE AND ITS POLYMER<br>N-(2-乙烯氧乙基)-1,8-萘二甲酰亚胺聚合物与共聚物的荧光行为
%A CAI Hui
%A LI Fu-mian
%A <br>蔡辉
%A 李福绵
%J 高分子学报
%D 1993
%I 
%X A novel functional monomer N-(2-Vinyloxyethyl)naphthalimide(VOENl) was synthesized and the photochemical behavior of its polymer was studied. With the electron-donating viny-loxyethyl group and the electron-accepting naphthalyl chromophore moiety coexisting in the same molecule, VOENI would form exciplex intermolecularly upon UV-irradiation and showed much lower fluorescence emission intensity compared with its polymer. Such a phenome-num was also termed as "Structural Self-Quenching Effect" similar to what had been reported previously in those structurally reversed cases of acrylic monomers bearing both electron-donating chromophore moiety and electron-accepting double bond in one molecule.
%K N-(2-Vinyloxyethyl)-1
%K 8-naphthalimide
%K Fluorescence emission spectrum
%K Fluorescence quenching
%K Structural Self-Quenching Effect<br>荧光光谱
%K VOENI
%K 高聚物
%K 共聚物
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=15971983683C7643EE80F1CE621DEB60&aid=B9B9392392723351546A615F9A7CE78B&yid=D418FDC97F7C2EBA&iid=0B39A22176CE99FB&sid=FD7C952458BFB5D8&eid=FBCA02DBD05BD4EA&journal_id=1000-3304&journal_name=高分子学报&referenced_num=2&reference_num=3