%0 Journal Article
%T Comparison of Activating Performance of Activators in Membrane Gas Absorption
膜基气体吸收过程中活化剂的活化性能比较
%A LU Jian-gang
%A ZHENG You-fei
%A CHEN Min-dong
%A HE Du-liang
%A ZHAO Xiao-li
%A ZHANG Hui
%A
陆建刚
%A 郑有飞
%A 陈敏东
%A 何都良
%A 赵晓莉
%A 张慧
%J 过程工程学报
%D 2007
%I
%X Piperazine (PZ) and 2-amino-2-methyl-1-propanol (AMP) as activators were added into methyldiethanolamine (MDEA) to form complex aqueous solutions, respectively. Mass transfer performance of CO2 absorption into the complex aqueous solutions in membrane contactors was studied. The effects of various factors, such as flowrates of gas and liquid, CO2 concentration of feed gas, absorbent concentrations of the solutions, CO2 loading in the solutions, configuration of membrane, and structures of modules on overall mass transfer coefficients of membrane contactors were investigated. Emphatically, the enhancement of mass transfer in membrane contactors was evaluated by means of comparison of chemical activation of sterically hindered amine AMP and multi-amino PZ in the complex solutions. The results show that multi-amino PZ has higher activation than sterically hindered amine AMP in complex solutions. The enhancement of PZ to mass transfer is higher than that of AMP in membrane contactors. The effect of hydrodynamics on mass transfer is limited. Chemical activation of activators is the key influential factor on mass transfer. Reaction kinetics plays a significant role in mass transfer.
%K membrane gas absorption
%K complex solutions
%K performance comparison
膜气体吸收
%K 复合溶液
%K 性能比较
%K 膜基
%K 气体
%K 吸收过程
%K 活化剂
%K 性能比较
%K Gas
%K Absorption
%K Membrane
%K Activators
%K Performance
%K 活化作用
%K 流体力学因素
%K 关键性因素
%K 化学
%K 有限
%K 活化效应
%K 空间位阻胺
%K 结果
%K 加强作用
%K 总传质系数
%K 环状结构
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=5B3AB970F71A803DEACDC0559115BFCF0A068CD97DD29835&cid=3FCF8B1A330466D5&jid=B9EE12934D19905403D996AE65CEEEED&aid=00401767E1A4E6BE3824702180C6335A&yid=A732AF04DDA03BB3&vid=DF92D298D3FF1E6E&iid=CA4FD0336C81A37A&sid=7C3A4C1EE6A45749&eid=BE33CC7147FEFCA4&journal_id=1009-606X&journal_name=过程工程学报&referenced_num=0&reference_num=18