%0 Journal Article %T THE KINETICS OF POLYESTERIFICATION, ESTERIFICATION, AND HYDROLYSIS OF ESTER
关于二元酸与二元醇的聚酯反应和酯化与水解反应动力学 %A LAI CHU-GEN %A LU JIA-LIN %A FANG YAO-REN %A BAO FI-YI %A
赖柱根 %A 卢迦陵 %A 房耀仁 %A 鲍甫义 %J 高分子学报 %D 1965 %I %X In polyesterification, the action of alcohol as a carrier of H+-ion was supposed to be negligable, in contrast to the result obtained by Tang Au-Ching. A new hypothesis of polyesterification was then suggested.This mechanism can be used to explain some other types of esterification as well. Favourable results were obtained even if p (the percent of the theoretical degree of reaction) is greater than 91%. In the hydrolysis of esters by using strong or weak acid as catalysts, results obtained were found to be better than those obtained by previous authors. %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=15971983683C7643EE80F1CE621DEB60&aid=2F5BE5931449A290&yid=DCB97F70EF167067&iid=B31275AF3241DB2D&sid=F4BDB5452F9F5642&eid=44FDB9366EDDFA2B&journal_id=1000-3304&journal_name=高分子学报&referenced_num=0&reference_num=0