%0 Journal Article
%T STUDIES ON ORGANIC PEROXIDE-DITERTIARY AMINE INITIATION SYSTEMS<br>有机过氧化物与二元叔胺引发体系的研究
%A Qiu Kun-yuan
%A Zhang Jing-yi
%A Hu Yuan-jie
%A Feng Xin-de
%A <br>丘坤元
%A 张景义
%A 胡元洁
%A 冯新德
%J 高分子学报
%D 1985
%I 
%X Radical polymerization of methyl methacrylate (MMA) initiated with organic pero-xide-ditertiary amine binary systems was studied in this paper. In order to study the effects of organic peroxide and amine respectively, benzoyl peroxide (BPO), lauroyl peroxide (LPO), t-butyl hydroperoxide (TBH), and t-butyl peroxybenzoate (TBPB) were used as organic peroxide component, and aromatic ditertiary amine 4,4'-tetramethyldia-minodiphenylmethane (TMDAPM), and aliphatic ditertiary amine tetramethylethylene-diamine (TMEDA) were used as amine component. It was found that in the bulk poly-merization of MMA using organuc peroxide-TMDAPM binary initiation systems,the ef-fect of organic peroxide on the polymerization rate of MMA Rp was in the following order:BPO>LPO>TBH>TBPB. However,in the organic peroxide-TMEDA binary systems,the order of Rp was LPO-TMEDA>TBH-TMEDA,and BPO-TMEDA,TBPB-TMEDA system could not initiate MMA polymerization. The values of Ea,overall activation energa of polymerization,of MMA initiated with organic peroxide-TMDAPM systems were determined. According to the kinetic studies of MMA polymerization initiated with BPO-TMDAPM,LPO-TMDAPM system,the foll-owing equations were obtained.
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=15971983683C7643EE80F1CE621DEB60&aid=365677667D18A69B&yid=74E41645C164CD61&iid=CA4FD0336C81A37A&sid=9FFCC7AF50CAEBF7&eid=1D0FA33DA02ABACD&journal_id=1000-3304&journal_name=高分子学报&referenced_num=0&reference_num=0