%0 Journal Article
%T Research on Curing of a Silicon-containing Arylacetylene Resin with Nickelous Diacetyl Acetonate<br>乙酰丙酮镍催化含硅芳炔树脂的固化反应行为
%A LIU Hai-fan
%A DENG Shi-feng
%A HUANG Fa-rong
%A DU Lei
%A <br>刘海帆
%A 邓诗峰
%A 黄发荣
%A 杜磊
%J 过程工程学报
%D 2012
%I 
%X The curing reaction of silicon-containing arylacetylene resin(PSA) with nickelous diacetyl acetonate(NIAA) was studied,the curing behavior was characterized by gelation time and DSC analysis,curing kinetic parameters were calculated,the curing was traced by FT-IR.The results indicated that the catalytic effect of NIAA on PSA resin was obvious.When 0.2%(ω) nickelous diacetyl acetonate was added in the resin,the apparent activity energy of curing reaction was decreased from 121.2 kJ/mol for PSA resin to 104.2 kJ/mol for PSA-NAA resin and the initial curing temperature decreased by 35℃.Glaser coupling,Strauss coupling,cyclotrimerization and Diels-Alder reaction occurred at different cuing stages of PSA-NIAA resin.The cured PSA?NIAA resin possessed excellent thermal stability.The temperature at 5% weight loss and char yield at 1000℃ of the cured resin with 0.2% NIAA were 620℃ and 87.8% under nitrogen,respectively.
%K silicon-containing arylacetylene resin
%K nickelous diacetyl acetonate
%K curing kinetics
%K curing mechanism
%K catalytic curing<br>含硅芳炔树脂
%K 乙酰丙酮镍
%K 固化反应动力学
%K 固化机理
%K 催化固化
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=5B3AB970F71A803DEACDC0559115BFCF0A068CD97DD29835&cid=3FCF8B1A330466D5&jid=B9EE12934D19905403D996AE65CEEEED&aid=28538CA98C300078BD7EB8570662E487&yid=99E9153A83D4CB11&vid=59906B3B2830C2C5&iid=CA4FD0336C81A37A&sid=E2546871E5B846EF&eid=BA79719BCA7341D5&journal_id=1009-606X&journal_name=过程工程学报&referenced_num=0&reference_num=0