%0 Journal Article %T THE STUDY OF THE EFFECT OF PVE ON POLYMERIZATIONOF N-SUBSTITUTED ACRYLAMIDE ANDINTERACTION BETWEEN THEM
聚乙烯醇对N-取代丙烯酰胺聚合反应的影响以及它们间相互作用的研究 %A Wang Shen-guo %A Xi Fu %A Li Zhi-fen %A
王身国 %A 习复 %A 李执芬 %J 高分子学报 %D 1984 %I %X Based on the results of earlier work, the effect of PVA on polymerization of N-substi-tuted acrylamide has been studied. It was found that the rate of polymerization of N-methy-lacrylamide decreased proportionally with the amount of PVA added in the system of polymerization. And there was no effect of PVA on polymerization of N, N-dimethylacrylamide. The interaction between N-methylacrylamide and 1,3-propanediol as a model of PVA has been investigated by means of (Chemical lonization) Mass Spectrometry. It showed a com-plex formation between them. The change of viscosity of PVA solution in presence of acry-lamide gives further evidences.The mechanism of complex formation was discussed. %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=15971983683C7643EE80F1CE621DEB60&aid=03E72AE0185330ED&yid=36250D1D6BDC99BD&iid=38B194292C032A66&sid=0584DB487B4581F4&eid=F1A8654ADB4E656E&journal_id=1000-3304&journal_name=高分子学报&referenced_num=0&reference_num=0