%0 Journal Article
%T Non-isothermal Decomposition Kinetics of Methyl N-Phenyl Carbamate for Preparation of Phenyl Isocyanate<br>苯氨基甲酸甲酯热解制备苯基异氰酸酯的非等温动力学
%A ZHU Gan-yu
%A LI Hui-quan
%A WU Hui-xiong
%A CAO Yan
%A LIU Hai-tao
%A LI Xin-tao
%A ZHANG Qin-hua
%A TANG Qing
%A <br>朱干宇
%A 李会泉
%A 邬慧雄
%A 曹妍
%A 柳海涛
%A 李新涛
%A 张琴花
%A 唐清
%J 过程工程学报
%D 2012
%I 
%X The decomposition process of methyl N-phenyl carbamate(MPC) was studied by TG-DTG,DSC and IR techniques.It is shown that the decomposition of MPC for generating phenyl isocyanate(PI) is one step with the generation of methanol gas.Then non-isothermal decomposition kinetics of MPC was studied.Flynn-Wall-Ozawa method was used to calculate the reaction activation energy,E,through the data of DSC/TG/DTG.The kinetic parameters were calculated using five kinetic analytical methods.The result indicated that the mechanism function of MPC decomposition was G(α)=α1/3,E and the pre-exponential factor,A,of the reaction were E=20.52 kJ/mol and lgA=2.23,respectively,and the kinetic equation could be expressed as α1/3=169.82exp20.52×10~3/(8.314T)]t.
%K methyl N-phenyl carbamate
%K non-isothermal
%K decomposition
%K kinetics
%K thermal analysis<br>苯氨基甲酸甲酯
%K 非等温
%K 热解
%K 动力学
%K 热分析
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=5B3AB970F71A803DEACDC0559115BFCF0A068CD97DD29835&cid=3FCF8B1A330466D5&jid=B9EE12934D19905403D996AE65CEEEED&aid=21CB0722CA48644FF4429D207AC5065E&yid=99E9153A83D4CB11&vid=59906B3B2830C2C5&iid=E158A972A605785F&sid=C7B13290323C226E&eid=EF9E84B2DA79FF23&journal_id=1009-606X&journal_name=过程工程学报&referenced_num=0&reference_num=0