%0 Journal Article
%T STUDIES ON THE PHOTO-COPOLYMERIZATION OF (4-VP)2 ZnCl2 WITH ELECTRON-DONATING MONOMERS
4-乙烯基吡啶-氯化锌络合物与电子给体单体光照下共聚合研究
%A LI Tong
%A ZHOU Chun-lin
%A
李橦
%A 周春林
%J 高分子学报
%D 1989
%I
%X The photo-induced copolymerization of the complex of 4-vinylpyridine and ZnCl2 (4-VP)2ZnCl2 (M1) as an electron-accepting monomer with the electron-donating monomer styrene (M2) was studied under the irradiation at 365 nm. The charge-transfer complex between them absorbs the light and then produces initiating radicals. The reactivity ratios were measured to be r1=2.04 and r2=0.24. The effect of the polarity of the solvents on the copolymerization and the photo-induced copolymerization of (4-VP)2 ZnCl2 with other electron-donating monomers were also investigated.
%K Photopolymerization
%K Copolymerization
%K 4-vinylpyridine strucluer
乙烯基吡啶
%K 光聚合
%K 共聚合
%K 苯乙烯
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=15971983683C7643EE80F1CE621DEB60&aid=C71650CF9C10407B227E744F49A44943&yid=1833A6AA51F779C1&iid=38B194292C032A66&sid=EC34D52BE81085CE&eid=4AD4BA66429F5627&journal_id=1000-3304&journal_name=高分子学报&referenced_num=0&reference_num=0