%0 Journal Article %T NEMATIC-ISOTROPIC PHASE EQUILIBRIA IN RIGID ROD-LIKE POLYMERS OF LOW D. P.
刚性棒状结构低聚体中的向列型液晶-各向同性相平衡 %A WU Da-cheng %A
吴大诚 %J 高分子学报 %D 1985 %I %X The thermotropic nematic-isotropic equilibria in an undiluted system of polydis-perse rod-like molecules obtained by melt polycondensations has been investigated both theoretically and experimentally. In this paper, effects of the polydispersity and orientation-dependent (i.e. anisotropic) interactions between rod-like molecules on the phase equilibria are included. It was shown in the experimental part of this work that the thermotropic nematic-isotropic equilibria will appear in the wide range of temperature for poly(p-hydroxybenzoates) samples with the average D.P. equal to approximately 3. %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=6579068328FE643F&jid=15971983683C7643EE80F1CE621DEB60&aid=1EB07FF565C4A3FA&yid=74E41645C164CD61&iid=0B39A22176CE99FB&sid=03F1579EF92A5A32&eid=4DB1E72614E68564&journal_id=1000-3304&journal_name=高分子学报&referenced_num=1&reference_num=0