%0 Journal Article %T Preparation and Characterization of LiNi0.8M0.2O2 with Various Doping Elements for Lithium Battery Cathod
锂离子电池正极材料LiNi0.8M0.2O2的制备 %A LI Hui %A YANG Shang-lin %A ZHAI Yu-chun %A TIAN Yan-wen %A
李辉,杨尚林,翟玉春,田彦文 %J 过程工程学报 %D 2002 %I %X With doping different elements (M), a series of compounds LiNi0.8M0.2O2 used as cathode materials in lithium ion batteries were prepared by solid reaction under increased oxygen pressure. It was found that the doped Al, Mn and Ti can improve the properties in overcharge tolerance and cyclic capacity. The discharge capacity was almost kept constant after three cycles at high charging voltage ranging from 4.2 to 4.8 V. XRD and SEM analyses revealed that doping Al, Mn and Ti increased the orderness of the LiNiO2 material in the hexagonal phase and maintained the layered structure during the charging/discharging process. However, doping other elements decreased the orderness of the material structure, which clearly affected the electrochemical properties of the materials. %K lithium ion battery %K cathode material %K doping %K oxygen pressure %K electrochemical properties
锂离子电池 %K 正极材料 %K 掺杂元素 %K 氧气压力 %K 电化学性能 %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=5B3AB970F71A803DEACDC0559115BFCF0A068CD97DD29835&cid=3FCF8B1A330466D5&jid=B9EE12934D19905403D996AE65CEEEED&aid=AD564C78B8BE4672&yid=C3ACC247184A22C1&vid=0B39A22176CE99FB&iid=B31275AF3241DB2D&sid=F204392B3B11C3BD&eid=AE43DE0664B02889&journal_id=1009-606X&journal_name=过程工程学报&referenced_num=1&reference_num=11