%0 Journal Article
%T Catalysis of Bismuth Complex Salt in Vapor Phase Hydrochlorination of Acetylene<br>铋复合盐在乙炔氢氯化反应中的催化作用
%A WEI Xiao-bo
%A WEI Fei
%A QIAN Wei-zhong
%A LUO Guo-huo
%A SHI Hai-bo
%A JIN Yong
%A <br>魏小波
%A 魏飞
%A 骞伟中
%A 罗国华
%A 师海波
%A 金涌
%J 过程工程学报
%D 2008
%I 
%X A non-merury novel catalyst with bimetallic chlorides and bimetallic phosphates based on SiO2 was prepared by dipping method and used in catalytic hydrochlorination of acetylene to vinyl chloride. The experimental results showed that reaction activity of the catalyst could be promoted obviously by introducing PO43- to it. Bimetallic phosphates of Cu and Bi based on SiO2 behaved the best in testing of catalysis, and its initial reaction activity was 1/3 time of conventional industrial HgCl2/C catalyst. The c...
%K vinyl chloride
%K hydrochlorination
%K acetylene
%K bismuth phosphate
%K non-mercury catalyst<br>氯乙烯
%K 氢氯化
%K 乙炔
%K 磷酸铋
%K 无汞催化刺
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=5B3AB970F71A803DEACDC0559115BFCF0A068CD97DD29835&cid=3FCF8B1A330466D5&jid=B9EE12934D19905403D996AE65CEEEED&aid=8E54C28ECF6A512E02E6A5BD4B5FAA3D&yid=67289AFF6305E306&vid=5D311CA918CA9A03&iid=B31275AF3241DB2D&sid=E2F55FDAFC844F27&eid=966030800FCA5D46&journal_id=1009-606X&journal_name=过程工程学报&referenced_num=2&reference_num=16