%0 Journal Article %T Electrocatalytic Activity of Ti/TiO2 Electrodes in H2SO4 Solution %A WANG Ya-qiong %A
WANG Ya-qiong王雅琼 %A TONG Hong-yang童宏扬 %A XU Wen-lin许文林 %J 过程工程学报 %D 2003 %I %X Ti/TiO2 electrodes were prepared with the polymeric precursor method (PPM). The structure and morphology of Ti/TiO2 electrodes were examined with XRD and ESEM. The voltammetric charge (q*) of Ti/TiO2 electrodes as cathode in 0.5 mol/L H2SO4 solution was investigated with cyclic voltammetry. It was found that the electrocatalytic activity of the Ti/TiO2 electrodes was affected by the structure and morphology of the Ti/TiO2 electrodes, in other words, was affected by the calcination conditions of preparing the electrodes. The value of q*ln was considerably larger than that of q*out,which means that the 'inner' active surface area was much larger than the 'outer' active surface area, and 'inner' active surface played a main role in the electrocatalytic activity of the Ti/TiO2 electrodes. %K voltammetric charge %K active surface %K TiO2 electrode %K electrochemistry
电极过程 %K 二氧化钛 %K 硫酸溶液 %K 电化学行为 %K XRD %K PPM %K 聚合前驱体 %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=5B3AB970F71A803DEACDC0559115BFCF0A068CD97DD29835&cid=3FCF8B1A330466D5&jid=B9EE12934D19905403D996AE65CEEEED&aid=2090C2CC8420008A&yid=D43C4A19B2EE3C0A&vid=38B194292C032A66&iid=E158A972A605785F&sid=35E8A259891FB32F&eid=5DCBAAB000A70168&journal_id=1009-606X&journal_name=过程工程学报&referenced_num=0&reference_num=13