%0 Journal Article
%T Thermodynamic Analysis of the Hydrogen-Carbon System for Acetylene Production by Plasma<br>等离子体裂解煤制乙炔碳-氢体系的热力学平衡分析
%A CHEN Hong-gang
%A XIE Ke-chang
%A <br>陈宏刚，谢克昌
%J 过程工程学报
%D 2002
%I 
%X In order to find the temperature range and initial reactant ratio for the maximum yield of acetylene, chemical thermodynamic equilibrium of heterogeneous multi-component C-H system was studied. All the thermodynamic equilibrium calculations are based on minimization of Gibbs free energy in the temperatures range from 500 K to 5000 K at intervals of 100 K. All species for which data are available in the JANAF Thermodynamic Tables are included in the C-H system. The Gibbs free energy minimization is expressed as a nonlinear optimization problem including equation and inequality constraints. The results show that it is irrational to consider the C-H system as homogeneous. Only the results from a heterogeneous system is realistic and reasonable and the best temperature range for acetylene formation is 3400~3800 K.
%K acetylene
%K thermodynamic equilibrium
%K heterogeneous multi component
%K Gibbs free energy
%K GRG method<br>等离子体
%K 裂解
%K 煤
%K 碳－氢体系
%K 乙炔
%K 热力学平衡
%K 多相多组份
%K Gibbs自由能
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=5B3AB970F71A803DEACDC0559115BFCF0A068CD97DD29835&cid=3FCF8B1A330466D5&jid=B9EE12934D19905403D996AE65CEEEED&aid=0E99A61B40DC6C0C&yid=C3ACC247184A22C1&vid=0B39A22176CE99FB&iid=0B39A22176CE99FB&sid=4BB057F167CF3A60&eid=7555FB9CC973F695&journal_id=1009-606X&journal_name=过程工程学报&referenced_num=3&reference_num=9