%0 Journal Article %T Removal of Arsenite and Arsenate from Solid Herb Samples by Supercritical CO2 Extraction with Ion-pairing
超临界CO2离子缔合萃取砷的实验 %A GUAN Yan-fen %A WANG Tao %A
关艳芬 %A 王涛 %J 过程工程学报 %D 2002 %I %X The removal of arsenite and arsenate from solid herb sample by ion-pairing supercritical CO2 extraction was explored. As a result of the insolubility of tetrabutylammonium bromide (Bu4NBr) in supercritical CO2, the extraction efficiency of supercritical extraction with non-in-situ retreatment of ion-pairing with Bu4NBr was much better than supercritical extraction with in situ ion-pairing. For the cases of non-in-situ ion-pairing, the extraction efficiency was strongly dependent on the total amount of Bu4NBr. The optimal amount of Bu4NBr was 130.0106 mol/g solid sample under the experimental conditions. %K ion-pairing %K supercritical CO2 %K extraction %K arsenite %K arsenate %K tetrabutylammonium bromide
离子缔合 %K 超临界CO2 %K 萃取 %K 砷 %K 四丁基铵 %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=5B3AB970F71A803DEACDC0559115BFCF0A068CD97DD29835&cid=3FCF8B1A330466D5&jid=B9EE12934D19905403D996AE65CEEEED&aid=CC878A02F943F3B6&yid=C3ACC247184A22C1&vid=0B39A22176CE99FB&iid=38B194292C032A66&sid=DC330B09A33F1455&eid=4E6F5C60B72D9B1C&journal_id=1009-606X&journal_name=过程工程学报&referenced_num=2&reference_num=9