%0 Journal Article
%T Spectrum Hyper-fine Structure and Zero-field Splitting Parameters with Jahn-teller Effect of CsNiCl3 Crystal<br>Ni2+：CsMgCl3晶体的光谱精细结构、零场分裂参量及Jahn-Teller效应
%A YIN Chun-hao
%A JIAO Yang
%A SONG Ning
%A RU Rui-peng
%A YANG Liu
%A ZHANG Lei
%A <br>殷春浩
%A 焦杨
%A 宋宁
%A 茹瑞鹏
%A 杨柳
%A 张雷
%J 光子学报
%D 2007
%I 
%X The 45 ranks complete diagonalized Hamiltonian matrixes of 3d2/3d8 ions configuration in the trigonal symmetry have been established by irreducible representation method. The spectra hyper-fine structure and the constants of crystal structure and zero-field splitting parameters of CsNiCl3 crystal doped with CsMgCl3 crystal have been studied as well as Jahn-Teller effect and the influence of the spin singlet to the ground levels of Ni2+ ion. The results agree with the experimental findings. Besides, taking into account the influence of the spin-spin (SS) coupling interactions and Trees correction omitted in previous publication.It is found that zero-field splitting parameters arise from five mechanisms; (1) Spin-orbit coupling mechanism; (2) Spin-spin coupling mechanism; (3) Spin-orbit and spin-spin combined coupling mechanism; (4) Spin-orbit and Trees correction combined coupling mechanism, (5)Spin-spin and Trees correction combined coupling mechanism. The spin-orbit coupling mechanism is the most important and other mechanisms can not be omitted.
%K Ground-state energy levels
%K Hyper-fine structure
%K Zero-field splitting
%K Spin-spin coupling<br>基态能级
%K 精细结构
%K 零场分裂
%K 自旋-自旋耦合
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=47EA7CFDDEBB28E0&jid=9F6139E34DAA109F9C104697BF49FC39&aid=C40AFDF8E5D1C4D613B6663CEE325872&yid=A732AF04DDA03BB3&vid=933658645952ED9F&iid=708DD6B15D2464E8&sid=5B4FE8EC29FFFACE&eid=7361423B3D179EDD&journal_id=1004-4213&journal_name=光子学报&referenced_num=0&reference_num=26