%0 Journal Article
%T CORROSION BEHAVIOR OF PATINATED BRONZE AND ITS PROTECTION IN ATMOSPHERE
已锈蚀青铜在大气环境中的腐蚀发展及其保护研究
%A WANG Ju-lin
%A XU Chun-chun
%A Yu Miao
%A
王菊琳
%A 许淳淳
%A 于淼
%J 腐蚀科学与防护技术
%D 2005
%I
%X Potentiodynamic scanning methods and cycle voltammetry (CV) technique were employed to study the electrochemical behavior of archaeological bronze in a medium (0.028 mol/L NaCl+0.01 mol/L Na_2SO_4+0.016 mol/L NaHCO_3) simulating atmosphere corrosion.The study focused on the protection performance provided by CuCl,Cu_2O,Cu_2(OH)_3Cl and mixed patina to bare bronze,and the results are that when the corrosion potentials are relatively negative,CuCl and Cu_2O respectively exibibit to be protective to bare bronze to certain extent,and they perform more effective than that of Cu_2(OH)_3Cl or mixed patina's.On the other hand when the corrosion potentials are relatively positive the protectiveness of CuCl or Cu_2O to bare bronze turn to poor and Cu_2(OH)_3Cl or mixed patina exhibit better protective to bare bronze than that of CuCl or Cu_2O.The 0.1%MBO (2-Mercaptobenzoxazole) alcohol solution can suppress anodic reactons of bare bronze or bronze covered with CuCl or Cu_2O to some extent and can obviovsly suppress that of bronze covered with Cu_2(OH)_3Cl or mixed patina.
%K archaeological bronze
%K environment
%K corrosion
%K inhibitor
%K 2-Mercaptobenzoxazole(MBO)
青铜
%K 环境
%K 腐蚀
%K 缓蚀剂
%K 2-巯基苯并恶唑(MBO)
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=5B3AB970F71A803DEACDC0559115BFCF0A068CD97DD29835&cid=AB188D3B70B071C57EB64E395D864ECE&jid=9F6E6EC8BA5BB62698F6640073DDD6E1&aid=85CDF67BA9541EC6&yid=2DD7160C83D0ACED&vid=BCA2697F357F2001&iid=94C357A881DFC066&sid=90612DF06FCE4D55&eid=170CE8B011EA4FD9&journal_id=1002-6495&journal_name=腐蚀科学与防护技术&referenced_num=2&reference_num=12