%0 Journal Article %T A M?ssbauer study of the magnetic coupling in iron phosphorous trisulfides
A Mossbauer study of the magnetic coupling in iron phosphorous trisulfides %A Dai Yao-Dong %A Wang Lin %A Yang Ya-Xin %A He Yun %A Huang Hong-Bo %A Xia Yuan-Fu %A
戴耀东 %A 王林 %A 杨亚新 %A 何云 %A 黄红波 %A 夏元复 %J 中国物理 B %D 2004 %I %X The polycrystalline sample of layered compound FePS_3 has been investigated by using M?ssbauer spectroscopy (12K to 300K), magnetic susceptibility measurements, x-ray diffraction and FTIR spectroscopy. The antiferromagnetic order exists below T_N=120.5±1K. The M?ssbauer spectra below T_N indicate that the magnetization axis is perpendicular to the layer of FePS_3, and the divalent iron cations are in their high spin configurations. By fitting the hyperfine field parameters near the Néel temperature, we obtain information on the nature of magnetic interactions in the material. The results show that the magnetic coupling can be treated by the two-dimensional Ising model, and it can be interpreted on the basis of a crystal-field effect. %K layered compound %K M?ssbauer spectroscopy %K magnetic coupling %K Ising model
Moessbauer光谱 %K 磁耦合 %K X射线衍射光谱 %K 三硫化亚磷铁 %K Ising模型 %K 多晶结构 %K 磁性材料 %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=47EA7CFDDEBB28E0&jid=CD8D6A6897B9334F09D8D1648C376FB4&aid=3DB5C598B1F65353D8FE277B91D5BD26&yid=D0E58B75BFD8E51C&vid=FC0714F8D2EB605D&iid=F3090AE9B60B7ED1&sid=1396DEC9DD671DC4&eid=4F4D699E68EBCB79&journal_id=1009-1963&journal_name=中国物理&referenced_num=0&reference_num=13