%0 Journal Article %T UV Spectral Analysis of the Chemical Modification and Photolysis of Acetylacetone Modified Alumina Aqueous Solution %A Chengbin JING %A Xiujian ZHAO %A Haizheng TAO %A Xina WANG %A Aiyun LIU %A
Chengbin JING %A Xiujian ZHAO %A Haizheng TAO %A Xina WANG and Aiyun LIU Key Laboratory of Silicate Materials Science and Engineering %A Ministry of Education %A Wuhan University of Technology %A Wuhan %A China %J 材料科学技术学报 %D 2004 %I %X Acetylacetone was firstly introduced into the aqueous media with the presence of aluminum sec-butoxide and peptizator. It was confirmed that the UV (ultraviolet) absorption band of acetylacetone underwent 14 nm of red-shift due to the formation of the six-membered ring of the complex between alumina and acetylacetone in the aqueous solution. It was also found that the chemical modification can be dissociated by the UV irradiation with a wavelength shorter than 286 nm as a result of the excitation of π-π* transition in the complex. %K Chemical modification %K Aluminum sec-butoxide %K Acetylacetone %K Photolysis
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=5B3AB970F71A803DEACDC0559115BFCF0A068CD97DD29835&cid=84529CA2B2E519AC&jid=324DC3CAB22330DB19158AE0A9B7BFA5&aid=C0D610805E4382C7&yid=D0E58B75BFD8E51C&vid=A04140E723CB732E&iid=94C357A881DFC066&sid=46C2A519EDDA03DD&eid=DB7B2C790D19BE6E&journal_id=1005-0302&journal_name=材料科学技术学报&referenced_num=0&reference_num=20