%0 Journal Article %T Influence of Ethylene Glycol on the Formation of Calcium Phosphate Nanocrystals %A Yi ZUO %A Yubao LI %A Jie WEI %A Yonggang YAN %A
YiZUO %A YubaoLI %A JieWEI %A YonggangYAN %J 材料科学技术学报 %D 2003 %I %X A synthesis route of using calcium hydroxide Ca(OH)2 with ethylene glycol solvent and orthophosphoric acid (H3PO4) as reagents is described. Three ratios of ethylene glycol to distilled water 1:0, 1:1 and 0:1 are used as diluting media for Ca(OH)2. Crystals of different morphology and composition are formed under weak alkaline circumstance at pH 7.0-8.0. Acicular calcium phosphate nanocrystals are prepared in pure ethylene glycol while rod-like calcium phosphate nanocrystals form in pure distilled water. The nanograde size of the former is smaller than that of the latter. Calcium-deficient apatite (CDAP) is obtained with a Ca/P molar ratio of 1.66. Therefore, it was deduced that the usage of ethylene glycol solvent could influence the formation of calcium phosphate crystal lattice. %K Acicular nanocrystals %K Calcium phosphate %K Ethylene glycol solvent %K Weak alkaline circumstance
乙烯 %K 乙二醇 %K 磷酸钙 %K 纳米晶体材料 %K 氢氧化钙 %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=5B3AB970F71A803DEACDC0559115BFCF0A068CD97DD29835&cid=84529CA2B2E519AC&jid=324DC3CAB22330DB19158AE0A9B7BFA5&aid=D25AC06D6C751473&yid=D43C4A19B2EE3C0A&vid=2A8D03AD8076A2E3&iid=B31275AF3241DB2D&sid=3EABEBD973E45554&eid=039DCCB9394D9766&journal_id=1005-0302&journal_name=材料科学技术学报&referenced_num=0&reference_num=33