%0 Journal Article
%T Fusion Equation of Metals
%A HONC Yongyan Zhejiang Institute of Technology
%A Hangzhou
%A China
%A <br>洪永炎
%J 材料科学技术学报
%D 1989
%I 
%X An expression of initial slope of meltingcurve of pure metals was obtained as follows:(dT_m/dP)_o=T_(mo)/c, where c=1.09 (N_(at))~(5/3)z~(-1/3),the unit of c is GPa, N_(at) is the atomic concentra-tion (in 10~(28) m~(-3)), z is the valence, T_(mo)is the melting temperature (in k) of metal underone atmosphere. The calculated results forthirty-one metals agree well with experiments.It has also been proved that by using the freeelectron model of melting, the fusion equationof metals is Simon equation (T_m/T_(mo))q=1+(p/d).Two parameters q and d, which have to fit withexperiments in Simon's empirical equation, nowcan be predicted theoretically, e.g. for Mg,giving q=1.56, d=7.88GPa, the calculated meltingcurve in a fairly wide pressure range (0～60GPa)is shown to be close to the experimental one.
%K melting curve of metals
%K free electron model<br>
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=5B3AB970F71A803DEACDC0559115BFCF0A068CD97DD29835&cid=84529CA2B2E519AC&jid=324DC3CAB22330DB19158AE0A9B7BFA5&aid=5C612BC4824DA92D&yid=1833A6AA51F779C1&vid=94C357A881DFC066&iid=0B39A22176CE99FB&sid=EFD65B51496FB200&eid=B62E0EEFE746E568&journal_id=1005-0302&journal_name=材料科学技术学报&referenced_num=0&reference_num=0