%0 Journal Article %T ELECTRICAL AND MAGNETIC PROPERTIES OF NEW POLYACENE QUINONE RADICAL POLYMERS
新型聚省醌自由基高聚物的电磁性能 %A LEI Qingquan %A ZHAO Xiaoxu %A FAN Yong %A ZHANG Weiguo %A
雷清泉 %A 赵晓旭 %A 范勇 %A 张维国 %J 材料研究学报 %D 1998 %I %X The several new polycene quinone radical (PAQR) co-polymers with very high Pressure resistivity coefficient were synthesized by condensation. It was experimentally found that a kink exists at about 0.11GPa on plots of log d.c. conductivity verses the square root of external pressure in a range from 0.01 to 1.0GPa; an applicable extent of Mott-T-1/4 law can expand to more high temperature region of 290-400K; there is an analogue trend of the changes between the d.c. conductivity and spin concentration and between g factor and peak-to-peak linewidth with mole fraction of 4,'4-(hexafluoroisopro-phlidene)-diphthalic anhydride (HFDA)introducecd;and the plot of log dielectric constant uersus the square root of external pressure at various temperatures does not fully obey the linear relationship theoretecally expected by Pohl. %K polyacene quinone radical polymer %K functional materials %K electro-magnetic behavior
聚省醌 %K 自由基 %K 高聚物 %K 功能材料 %K 电磁性能 %K PAQR %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=5B3AB970F71A803DEACDC0559115BFCF0A068CD97DD29835&cid=84529CA2B2E519AC&jid=C101C4C04993B4D94FCD8446E6CBEB3B&aid=7ABFB28A96E67B51&yid=8CAA3A429E3EA654&vid=59906B3B2830C2C5&iid=B31275AF3241DB2D&sid=00520952CD4BF212&eid=A0C7970CD30381EA&journal_id=1005-3093&journal_name=材料研究学报&referenced_num=0&reference_num=1