%0 Journal Article %T Steady State and Time-Resolved Fluorescence Dynamics of Triphenylamine Based Oligomers with Phenylene/Thiophene/Furan in Solvents
%A ZENG Qi %A LIU Ying-Liang %A MENG Kang %A ZHAO Xiang-Jie %A WANG Shu-Feng %A GONG Qi-Huang %A
%J 中国物理快报 %D 2009 %I %X We investigate the photo-physical properties of a series of triphenylamine-based oligomers by steady-state and picosecond transient fluorescence measurements in solvents. The oligomers are composed alternatively with triphenylamine and phenylene/thiophene/furan group, bridged by vinyl group (PNB/PNT/PNF). Their fluorescence spectra show bathochromic phenomenon with solvent polarity and viscosity increasing. The fluorescence decays are bi-exponential for PNB and PNT, and tri-exponential for PNF in THF and aniline. The strong viscosity dependence suggests conformational relaxation along the PNF chain after photo excitation. %K 78 %K 47 %K Jc %K 78 %K 40 %K Me %K 36 %K 20 %K Ey
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=47EA7CFDDEBB28E0&jid=E27DA92E19FE279A273627875A70D74D&aid=7DC94F873403C738AFC22B6FB81ECF8C&yid=DE12191FBD62783C&vid=96C778EE049EE47D&iid=DF92D298D3FF1E6E&journal_id=0256-307X&journal_name=中国物理快报&referenced_num=0&reference_num=0