%0 Journal Article
%T FORMATION AND STRUCTURE OF CUPROUS ION-CONDUCTING GLASSES IN THE SYSTEM CuI-Cu_2O-WO_3
CuI—Cu_2O—WO_3系统中亚铜离子传导玻璃的形成和结构
%A LI Guangming GAN Fuxi
%A
李光明
%A 干福熹
%J 材料研究学报
%D 1991
%I
%X The formation of new cuprous ion-conducting glasses in the systemCuI-Cu_2O-WO_3 was investigated by twin-roller quenching technique.The major glassforming region was found in the binary oxide system Cu_2O-WO_3 and the pseudobinarysystem CuI-Cu_2WO_4,respectively.The glass transition temperature (Tg) and thecrystallization temperature (T_c) were determined by differential thermal analysis (DTA),which reveal the existence of some metastable crystalline phases.The IR and Ramanspectra indicated that the glasses mainly consist of discrete ions Cu~+,I~-,WO_4~(2-) and a cer-tain amount of W_2O_7~(2-) groups.
%K twin-roller quenching
%K Cu~+ ion-conducting glasses
%K glass formation and structure
%K tungstate glasses
双辊急冷
%K Cu~+离子导电玻璃
%K 玻璃形成和结构
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=5B3AB970F71A803DEACDC0559115BFCF0A068CD97DD29835&cid=84529CA2B2E519AC&jid=C101C4C04993B4D94FCD8446E6CBEB3B&aid=DB9FC65F9A956798&yid=116CB34717B0B183&vid=94C357A881DFC066&iid=0B39A22176CE99FB&sid=04445C1D2BDA24EE&eid=0B4F496D54044D86&journal_id=1005-3093&journal_name=材料研究学报&referenced_num=0&reference_num=1