%0 Journal Article
%T SYNTHESIS OF A NEW C10 HIGHER CARBON SUGAR AND ITS STRUCTURE ELUCIDATION BY NMR AND ESI-MS/MS<br>新型C10高碳糖的NMR和-ESI-MS/MS研究
%A ZOU Da-peng
%A KANG Jian-xun
%A LIU Hong-min~
%A XU Wei-chao
%A ZHANG Hui-jun
%A ZHANG Bi
%A <br>邹大鹏
%A 康建勋
%A 刘宏民
%A 许卫超
%A 张慧君
%A 张碧
%J 波谱学杂志
%D 2004
%I 
%X PDC is commonly used to oxidate the hydroxy residue in carbohydrates to produce the corresponding ketone. Treatment of 1, 2-isopropylidene-5-O-benzoyl-α-D-xylofuranose with PDC in CH2Cl2 usually yields ketone. It was found in this study, however, a new type higher carbon sugar was obtained when the solvent in the above reaction was changed. The structure of the new higher carbon sugar was elucidated by NMR and ESI-MS/MS. The complete assignment of 1H and 13C NMR chemical shifts of this compound was obtained using 2D NMR techniques, including 1H-1H COSY, HMQC and HMBC.
%K NMR
%K ESI-MS/MS<br>归属
%K 高碳糖
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=47EA7CFDDEBB28E0&jid=1A3C8C6E452BD1AF5A6B6B99BA3989C9&aid=2165B48456CC918C&yid=D0E58B75BFD8E51C&vid=659D3B06EBF534A7&iid=E158A972A605785F&sid=21D8CE17EE5EE354&eid=1E9426A299DC9FFD&journal_id=1000-4556&journal_name=波谱学杂志&referenced_num=1&reference_num=6