%0 Journal Article %T The Structure of a Furanosesquiterpenoid Extracted from Myrrh Elucidated by NMR Spectroscopy
没药中一呋喃倍半萜的核磁共振研究 %A YANG Guo-chun %A LI Zhan-lin %A LI Wen %A HUA Hui-ming %A
杨国春 %A 李占林 %A 李文 %A 华会明 %J 波谱学杂志 %D 2008 %I %X A furanosesquiterpenoid, 2-methoxy-5-acetoxy-furanogermacr-1(10)E-en-6- one was isolated from the CHCl3 extrct of myrrh. Its structure was established by its 1D and 2D NMR (i.e, 1H-1H COSY, HSQC and HMBC) spectra. The 1H and 13C chemical shifts of the compound were assigned. The relative stereochemistry of the 1, 10-double bond and that of the methoxyl, methyl, and acetoxy groups were determined by NOESY experiments and analyses of the coupling constants. %K NMR %K 2D NMR
归属 %K 没药 %K 呋喃倍半萜 %K 相对构型 %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=47EA7CFDDEBB28E0&jid=1A3C8C6E452BD1AF5A6B6B99BA3989C9&aid=5E4C4DA21C89353EAF2EF0CB45DE5BB8&yid=67289AFF6305E306&vid=C5154311167311FE&iid=E158A972A605785F&sid=1918ADDC93A85779&eid=E5D85F291CED2DA6&journal_id=1000-4556&journal_name=波谱学杂志&referenced_num=0&reference_num=8