%0 Journal Article %T Synthesis of Core/Shell Calcium Carbonate Peanut-like Assemblies in Polyacrylamide Aqueous Solution
PAM溶液中合成核/壳结构花生状碳酸钙粒子 %A JIANG Xi-Hua %A ZHENG Ming-Bo %A CHEN Hui-Qin %A PAN Li-Jia %A TAO Jie %A CAO Jie-Ming %A
蒋锡华 %A 郑明波 %A 陈惠钦 %A 潘力佳 %A 陶杰 %A 曹洁明 %J 无机材料学报 %D 2008 %I Science Press %X Peanut-like CaCO3 assemblies with core-shell structure were obtained in polyacrylamide aqueous solution. The as-prepared products were characterized by scanning electron microscope (SEM), transmission electron microscope (TEM), and X-ray diffraction (XRD). The results indicate that the peanut-like CaCO3 assemblies has some hollows. The shell of the CaCO3 assemblies is composed of calcite rhombohedras, and the core of the CaCO3 assemblies is composed of rod-like aggregates which are assembled by small particles and the core has a radially outward growth structure. The radially outward structure of the core is explained by the fractal growth theory, and the formation of Core/Shell structure is explained by the Ostwald ripening theory. %K CaCO3
核/壳结构 %K 分形生长 %K 熟化理论 %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=5B3AB970F71A803DEACDC0559115BFCF0A068CD97DD29835&cid=84529CA2B2E519AC&jid=ABC0063016AF57E1C73EF43C8D2212BD&aid=AC5F6EB27D3BED93739D8F92F91E0A5C&yid=67289AFF6305E306&vid=EA389574707BDED3&iid=B31275AF3241DB2D&sid=2F8F471CEC23CD85&eid=F7C51083F4D893E5&journal_id=1000-324X&journal_name=无机材料学报&referenced_num=0&reference_num=21