%0 Journal Article %T A Study on Conductivity of (Zr1-xMx)O2 Ceramic
(Zr1-xMx)O2陶瓷的电导性能研究 %A LI Fushen %A CHEN Ning %A LI Lifen %A LI Yang %A
李福燊 %A 陈宁 %A 李丽芬 %A 李阳 %J 无机材料学报 %D 1997 %I Science Press %X In the ZrO_2 ceramic systems doped with different oxides (Y_2O_3, MgO and Al_2O_3), the electronic energy spectroscopy and local density of states were calculated by a theoretical quantumchendcal method, and compared with the behaviors of electronic and ionic conduction. The resultsshowed that for the system doped with Al_2O_3, the energy gap near the Fermi energy level becomessmaller, so that the electronic couduction increases; the binding energy between Al and O atomincreases, which enhances the energy for vacancy migrating, the ionic conduction decreases. Onthe coutrary the systems doped with Y_2O_3 show a large ionic conduction, but a weaker electronicconduction. The effect of MgO is just between above two systems. The mentioned results agreewith that of references and experiments. %K 氧化锆 %K 掺杂 %K 电导 %K 氧化物陶瓷 %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=5B3AB970F71A803DEACDC0559115BFCF0A068CD97DD29835&cid=84529CA2B2E519AC&jid=ABC0063016AF57E1C73EF43C8D2212BD&aid=76EBA4C8813A57858713B0C75D192F69&yid=5370399DC954B911&vid=59906B3B2830C2C5&iid=B31275AF3241DB2D&sid=138D3449C4A7D4E9&eid=8D95DD1211171525&journal_id=1000-324X&journal_name=无机材料学报&referenced_num=0&reference_num=6