%0 Journal Article
%T Effects of Adding Organic Amine on the Synthesis of TS Zeolitesand Catalytic Properties<br>添加有机胺对钛硅沸石的合成和催化性能的影响
%A FU Zai--Hui
%A YIN Du-Lina
%A ZHANG Lu-Xi
%A ZHANG You-Yu
%A WAN Yan
%A <br>伏再辉
%A 尹笃林
%A 张鲁西
%A 张友玉
%A 万言
%J 无机材料学报
%D 1998
%I Science Press
%X Titanium-substituted silicate was synthesized by using tetrabutylammonium hydroxide(TBAOH), TS-2 mother liquor (ML), as well as ML and other organic amine as templating agentsrespectively. In this system, TBA canons serve as templating effects to direct the MEL structure,and then the templating agents of TBAOH, ML, or ML TEAOH (tetraethylammonium hydroxide) could ail induce to produce TS-2 zeolites, but adding TEAOH into ML obviously enhancedthe crystallinity and framework titanium content of TS-2, and obtained a very large crystal;adding ethylenediajmine (EDA) into ML could induce to produce a few of TS-1 crystal; addingn-Dipropylamine (DPA) into ML completely induced to produce TS-1 zeolite. These zeolites werefound to show a different activity in the hydroxylation of phenol with aqueous hydrogen peroxideand the reaction of isomerizing styrene Oxide to g-phenylaldehydes.
%K TS zeolites
%K synthesis
%K mother liquor
%K organic amine
%K templating effects
%K phenolhydroxylation
%K styrene oxide rearrangement<br>钛硅沸石
%K 合成
%K TS-2母液
%K 有机胺
%K 苯酚羟基化
%K 氧化苯乙烯重排
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=5B3AB970F71A803DEACDC0559115BFCF0A068CD97DD29835&cid=84529CA2B2E519AC&jid=ABC0063016AF57E1C73EF43C8D2212BD&aid=EB290F7852E805ED88EAC8EFBEEE8C86&yid=8CAA3A429E3EA654&vid=FC0714F8D2EB605D&iid=E158A972A605785F&sid=90773C2285A2F0BB&eid=4964C30D71DF45FF&journal_id=1000-324X&journal_name=无机材料学报&referenced_num=2&reference_num=10