%0 Journal Article %T Hydrophobic Sio2 Aerogels Prepared with Polyethoxydisiloxanes
疏水型SiO2气凝胶 %A DENG Zhong-Sheng %A WEI Jian-Dong %A Wu Ai-Mei %A BAO Yu-Ping %A WANG Jue %A SHEN Jun %A ZHOU Bin %A CHEN Ling-Yan %A
邓忠生 %A 魏建东 %A 吴爱梅 %A 暴玉萍 %A 王珏 %A 沈军 %A 周斌 %A 陈玲燕 %J 无机材料学报 %D 2000 %I Science Press %X Hydrophobic SiO2 aerogels were produced by the surface modification of alcogels prepared via sol-gel process using polyethoxydisiloxanes (E-40) as the precursor and followed by ethanol supercritical drying. The structure of the modified silica aerogels was a silica matrix produced by hydrolysis and condensation of polyethoxydisiloxanes. Si-CH3 was modified on the surface of the silica matrix. The pore size decreased from 23.1nm to 18.2nm, the specific surface area increased from 477 m2·g-1 to 563 m2·g-1 and the water vapor adsorption decreased from 0.04 to 0.0012(weight ratio) after the surface modification of silica aerogels. The existence of Si-CH3 was observed using infrared spectra. %K hydrophobic %K SiO2 aerogel %K sol-gel %K surface modification %K super critical drying
气凝胶 %K 表面修饰 %K 超临界干燥 %K 二氧化硅 %K 疏水型 %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=5B3AB970F71A803DEACDC0559115BFCF0A068CD97DD29835&cid=84529CA2B2E519AC&jid=ABC0063016AF57E1C73EF43C8D2212BD&aid=A045A6E393618A38&yid=9806D0D4EAA9BED3&vid=23CCDDCD68FFCC2F&iid=0B39A22176CE99FB&sid=B9B90065CF5CD7F0&eid=05340B75C67FF664&journal_id=1000-324X&journal_name=无机材料学报&referenced_num=9&reference_num=3