%0 Journal Article
%T Preparation, Characterization and Catalytic Properties of CuCl14PC/Y Nano-Composite<br>CuCl14Pc/Y纳米复合材料的制备、表征及其催化性能的研究
%A YANG Huai-Xin
%A LI Rui-Feng
%A DU Jun
%A FAN Bin-Bin
%A XIE Ke-Chang
%A <br>杨槐馨
%A 李瑞丰
%A 杜君
%A 范彬彬
%A 谢克昌
%J 无机材料学报
%D 2002
%I Science Press
%X Well-crystallized CuCl14PC/zeolite Y nano-composite of average particle size about 60nm (denoted as CuCl14PC/nano-Y) was successfully synthesized via zeolite synthesis method. The integrity of the nano-zeolite host was confirmed by XRD and TEM. The CuCl14PC complexes entrapped in the nano-hosts were characterized by XRD, TEM, FTIR, TG/DTA, ICP, and UV-vis. CuCl14PC/Y samples with different particle sizes in micro-scale were also synthesized by adjusting the temperature and water content. CuCl14PC in nano-Y exhibits the catalytic activity 3.1 times higher than CuCl14PC in normal Y with particle size of 550nm for the liquid phase oxidation of cyclohexane with aqueous H2O2 due to bigger surface areas and shorter diffusion pathways.
%K CuCl14PC
%K zeolite
%K nanocrystalline
%K cyclohexane oxidation<br>CuCl14Pc／Y
%K 纳米复合材料
%K 制备
%K 表征
%K 催化性能
%K 铜酞菁
%K 分子筛
%K 环己烷
%K 氧化反应
%K 催化剂
%U http://www.alljournals.cn/get_abstract_url.aspx?pcid=5B3AB970F71A803DEACDC0559115BFCF0A068CD97DD29835&cid=84529CA2B2E519AC&jid=ABC0063016AF57E1C73EF43C8D2212BD&aid=8DD8324EE98E5E42&yid=C3ACC247184A22C1&vid=BCA2697F357F2001&iid=38B194292C032A66&sid=92DA076AF6760FAC&eid=B34BDD6A690A04C0&journal_id=1000-324X&journal_name=无机材料学报&referenced_num=4&reference_num=18