%0 Journal Article %T Surface crystallization of amorphous fused silica during electron cyclotron resonance plasma etching
非晶熔石英表面等离子体刻蚀过程 中的表面晶化研究 %A Wang Feng %A Wu Wei-Dong %A Jiang Xiao-Dong %A Tang Yong-Jian %A
王锋 %A 吴卫东 %A 蒋晓东 %A 唐永建 %J 物理学报 %D 2012 %I %X After low pressure fluorine plasma ecthing and oxygen ion passivation,a crystallized layer composed of SiO2 nano-crystal grains is observed in an amorphous fused silica surface.The depth of crystallized layer is at least several hundreds nanometers.Fluorine and carbon ion are generated from Ar/CF4 by the method of electron cyclotron resonance(ECR).F ion breaks Si-O band of initial silica surface layer and releases O ion.Carbon ion combines with oxygen ion,and turns into CO2,and SiF4 is generated from fluorine and silicon.After initial surface layer is removed,unsaturated Si atom remains.Si dangling bond recombines with new O ion and then creates crystallizedα-cristobalite nano-crystal grains under a high temperature. %K amorphous fused silica %K crystallized a-cristobalite %K low pressure plasmas etching
非晶态熔石英 %K 结晶态α %K 方石英 %K 低压等离子刻蚀 %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=47EA7CFDDEBB28E0&jid=29DF2CB55EF687E7EFA80DFD4B978260&aid=4C92C33EB4B06FC5C32841075D594F53&yid=99E9153A83D4CB11&vid=1D0FA33DA02ABACD&iid=0B39A22176CE99FB&sid=6C55B56E28EED662&eid=6C55B56E28EED662&journal_id=1000-3290&journal_name=物理学报&referenced_num=0&reference_num=18