%0 Journal Article %T Non-solvent addition induced self-organization for enhancement of performance of poly(3-hexylthiophene) organic field-effect transistors
非溶剂掺杂完善自组织机理提升高度区域规则的(3-己基噻吩)有机场效应晶体管器件性能的研究 %A Tian Xue-Yan %A Zhao Su-Ling %A Xu Zheng %A Yao Jiang-Feng %A Yao Jiang-Feng %A Zhang Fu-Jun %A
田雪雁 %A 赵谡玲 %A 徐征 %A 姚江峰 %A 张福俊 %A 徐叙瑢 %J 物理学报 %D 2011 %I %X In order to enhance the performance of poly(3-hexylthiophene) (RR-P3HT) organic field-effect transistors (OFET) by low temperature solution-process of non-solvent addition (acetonitrile and ethanol), the resulting self-organization of polymer semiconductor layer and performance of RR-P3HT OFET are studied in this paper. The results fshow that an appropriate non-solvent addition (acetonitrile and ethanol) promotes the formation of more microcrystalline lamellae and improves the self-organization of polymer semiconductor layer, resulting in electrical properties enhancement of polymer OFET. The results indicate that the field-effect of RR-P3HT OFET with 5% acetonitrile addition can reach 3.39×10-3 cm2/V ·s, which is higher by a factor of 8 than that with 0% acetonitrile addition. Encessive non-solvent addition (acetonitrile and ethanol) leads to more precipitates which reduce microcrystalline lamellae and lowers the quality of polymer film, resulting in performance degradation of polymer OFET. %K regioregular poly(3-hexylthiophene) organic field-effect transistor %K non-solvent addition %K self-organization %K field-effect mobility
高度区域规则的聚(3-己基噻吩)有机场效应晶体管 %K 非溶剂掺杂 %K 自组织机理 %K 场效应迁移率 %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=47EA7CFDDEBB28E0&jid=29DF2CB55EF687E7EFA80DFD4B978260&aid=52D8C688FFDF5F5884782B462D70AD09&yid=9377ED8094509821&vid=BFE7933E5EEA150D&iid=38B194292C032A66&sid=867614A27AB666B2&eid=E04FC1B5BC47587B&journal_id=1000-3290&journal_name=物理学报&referenced_num=0&reference_num=19