%0 Journal Article %T The microstructure and properties of tetrahedral amorphous carbon films deposited by filtered arc with accelerating at different energetic grades
不同能级加速过滤电弧沉积四面体非晶碳膜的结构和性能 %A Zhu Jia-Qi %A Wang Jing-He %A Meng Song-He %A Han Jie-Cai %A Zhang Lian-Sheng %A
朱嘉琦 %A 王景贺 %A 孟松鹤 %A 韩杰才 %A 张连生 %J 物理学报 %D 2004 %I %X Tetrahedral amorphous carbon (ta-C) films were deposited on single crystalline silicon by accelerating the species with different impinging energetic grades produced by static-electricity pulse substrate bias from 0 to -2000 V. The microstructure of the ta-C films consist of amorphous sp3 hybridization skeleton enchased with sp2 clusters with sizes less than 1 nm by visible Raman measurement. At low energetic grade, sp3-rich energetic window, and sub-high energetic grade, the more the content of sp3 in the film, the smoother the surface of the film. The relationship between the impinging energy of the species and the surface morphology can be illustrated perfectly in the light of subimplantation growth mechanism. Nevertheless, at high energetic grade, the impinging ions with appropriate energy and angle can sputter and smoothen the surface, even the roughness is lower than the surface of the films with the most sp3. The hardness and Young's modulus of the films deposited at high energetic grade (-2000 V) are higher than those of the films prepared on the floating conditions. At the same time, the critical scratching load of the films deposited with the substrate bias of -2000 V is even larger than the one of the sp3-rich films. %K tetrahedral amorphous carbon (ta-C) %K filtered cathodic vacuum arc %K energetic grade
四面体非晶碳, %K 过滤阴极真空电弧, %K 能级 %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=6E709DC38FA1D09A4B578DD0906875B5B44D4D294832BB8E&cid=47EA7CFDDEBB28E0&jid=29DF2CB55EF687E7EFA80DFD4B978260&aid=C2A4F6280E7E1C62&yid=D0E58B75BFD8E51C&vid=8E6AB9C3EBAAE921&iid=E158A972A605785F&sid=19E8BB8BE90732B2&eid=59B00AA7F83CF649&journal_id=1000-3290&journal_name=物理学报&referenced_num=6&reference_num=33