%0 Journal Article %T Study on Enhanced Solubilization and Desorption Behavior of Anthrancene with Glycine-β-cyclodextrin
甘氨酸-β-环糊精对蒽的增溶、解吸行为研究 %A HUANG Lei %A WANG Guang-hui %A YU Rong %A DENG Nan-sheng %A
黄 磊 %A 王光辉 %A 于 荣 %A 邓南圣 %J 土壤 %D 2011 %I %X To improve the water solubility of β-cyclodextrin,β-cyclodextrin reacted with glycine in the presence of KOH and epichlorohydrin in water,a high water soluble glycine-β-cyclodextrin was prepared.Glycine-β-cyclodextrin for enhancing the solubilization and desorption behavior of anthrancene in soil were studied.The influence factors on desorption of anthrancene,such as pH,initial concentration of glycine-β-cyclodextrin,temperature and CD type were also investigated and described in details.The results showed that glycine-β-cyclodextrin has obvious solubilization for anthrancene,the solubility of anthrancene in 50 g/L of glycine-β-cyclodextrin was enhanced about 20-fold,the desorption efficiency of glycine-β-cyclodextrin for anthrancene in soil decreases with increasing pH,high temperature and initial concentration of glycine-β-cyclodextrin were beneficial to the desorption of anthrancene in soil,the desorption efficiency of glycine-β-cyclodextrin for anthrancene in soil was higher than those of α-cyclodextrin and β-cyclodextrin for anthrancene in soil and the desorption of glycine-β-cyclodextrin for anthrancene in soil followed the pseudo-second-order rate equation.This static desorption research could provide some fundamental information for the remediation of anthrancene-contaminated soil. %K Anthrancene %K Glycine-β-cyclodextrin %K Ehanced solubilization %K Desorption
蒽 %K 甘氨酸-β-环糊精 %K 增溶 %K 解吸 %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=03F54A49DE00578AA0E5DDF5BC021AA7&cid=1A8B5357F0EF07B8&jid=56F69E970C6E5190CDB409D28DD0E3C6&aid=4CE7EE22674152E0BB390DF0471674EA&yid=9377ED8094509821&vid=BE33CC7147FEFCA4&iid=0B39A22176CE99FB&sid=B799C1769FCACDC8&eid=96A53C367B5173D7&journal_id=0253-9829&journal_name=土壤&referenced_num=0&reference_num=21